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Contact with HF does not cause an immediate burning sensation or pain but readily penetrates deep tissue and causes intense pain after an hour or more. HFA is one of the strongest and most corrosive acids known, and is highly irritating, corrosive, and poisonous. April 26, 2022 WebThe article was published on 2012-12-12. Layaway Terms: A 25% down payment is required on all layaway items. In the first stage preheated fluorspar and preheated sulfuric acid are mixed together. U.S. Department of Health, Education, and Welfare. Future research might include testing whether fluorine can be extracted economically from high-pH, sodium-carbonate brines and exploring for new occurrences of apparently conformable fluorspar deposits in tuffaceous limy lacustrine sediments outside of the Latium Region of Italy. HFA toxicity occurs after ingestion, inhalation, or ocular or dermal contact. Mongolia produces and exports copper concentrate, coal, iron, fluorspar, gold, silver, uranium, and zinc. Its effects can range from occasional joint pain or stiffness to osteoporosis, muscle wasting, and neurological defects [1,45]. WebIt is used mainly in the chemical industry to manufacture hydrofluoric acid (HF). The products that contain the mineral of diamond are: It includes carbon which is a native element with the crystal system of isometric. WebDuring digestion of apatite with sulfuric acid to make phosphoric acid, hydrogen fluoride is produced as a byproduct from any fluorapatite content. Analysis, Treatise on Geochemistry (Second Edition), Encyclopedia of Toxicology (Second Edition), Microwave-Assisted Sample Preparation for Trace Element Analysis, Group 17 (H, F, Cl, Br, I) Alkaline Earth Compounds, Encyclopedia of the Alkaline Earth Compounds, HF is a solution of hydrogen fluoride in water. At least seven classes (which include one subclass) of hydrothermal fluorite deposits are recognized; they are classified according to their tectonic and (or) magmatic settings, as follows: (1) carbonatite-related fluorspar deposits; (2) alkaline-intrusion-related fluorspar deposits; (3) alkaline-volcanic-related epithermal fluorspar deposits; (4) Mississippi Valley-type fluorspar deposits (and a subclass of salt-related carbonate-hosted fluorspar deposits); (5) fluorspar deposits related to strongly differentiated granites; (6) subalkaline-volcanic-related epithermal fluospar deposits; and (7) fluorspar deposits that appear to be conformable within tuffaceous limy lacustrine sediments. [, Tan I, Lomasney L, Stacy GS, Lazarus M, Mar WA. The most common amount of fluoride in supplements is 0.25 mg, although a few products contain 0.5 or 1 mg [17]. Fluoride has no known, clinically relevant interactions with medications [59]. . Systematic Review of Fluoride Exposure and Neurodevelopmental and Cognitive Health Effects. A clear advantage of NH4F-assisted acid digestion is that it does not require handling the very corrosive and toxic HF. HF by itself is more effective in the digestion of silicate rock minerals than when mixed with another acid. Medications can contain fluoride. Fluoride dietary supplements in pregnant women: Like other nutrients, fluoride is transferred from a pregnant woman to her fetus, so a few studies have evaluated the use of fluoride supplements by pregnant women to prevent dental caries in their children. Recently, it has even been used in Car-Wash facilities in wheel cleaner compounds. Fluoride in Drinking Water: A Scientific Review of EPA's Standards. This study assessed caries rates in 798 3-year-old children whose mothers had received 1 mg/day fluoride during the last 6 months of pregnancy [35]. Single- or few-layer MXenes are produced by mechanically exfoliating or chemically delaminating the multilayered MXenes. [, Green R, Lanphear B, Hornung R, Flora D, Martinez-Mier EA, Neufeld R, et al. JAMA Pediatrics 2020;174:211-2. Any chemical compound that contains the fluoride ion is also known as a fluoride, such as calcium fluoride (CaF2) and sodium fluoride (NaF). Size: 24.0 x 18.0 x 9.0 cm (large-cabinet), Origin: Minerva Mine #1, Hardin Co., Illinois, USA, Number: (4711023) In the geological world, apatite is used for fission track dating, a technique that determines the age of a mineral sample by its uranium content. Cressey P, Gaw S, Love J. Association Between Maternal Fluoride Exposure During Pregnancy and IQ Scores in Offspring in Canada. After separation from the solids, the gases are treated with sulfuric and oleum to afford anhydrous HF. Fluorite is a soft rock which can be scratched with a Previously allowable levels ranged from 0.8 to 1.7 mg/L. In this study, the flotation tests on fluorite, quartz and a weight equivalent mixture (all less than 10 m) using water glass (with different modulus) as depressants and These organic molecules are difficult to remove, which negatively impacts the electrochemical performance of the MXene-based electrodes by reducing the conductivity and impeding ion transport. A molten mixture of these solids serves as a high-temperature solvent for the production of metallic aluminum. Failure to make any monthly payment by the scheduled date will result in forfeiture of any monies previously paid for the item or items. [, Featherstone JD. The fluoride additives used to fluoridate drinking water in the United States are fluosilicic acid, sodium fluosilicate, and sodium fluoride [14]. [. Eight minerals or mineral groups have sufficient fluorine in their structures to be considered as possible ores of the element; they are bastnaesite (also spelled bastnsite; and other fluorocarbonates), cryolite, sellaite, villiaumite, fluorite, fluorapatite (in phosphorites), various phyllosilicates, and topaz. The results showed no significant difference in the proportions of children who had decayed or filled primary tooth surfaces or who had caries. Examples are halite (NaCl), cryolite (Na 3 AlF 6 ), and fluorite (CaF 2 ).
Secure .gov websites use HTTPS Compared with the HF etching, the mild etchants contain cations (e.g., Li+, Na+, and NH4+) that can intercalate simultaneously into the interlayers of MXenes, leading to a more open layered structure. WebThe main fluorite-containing mineral is fluorspar, CaF 2. Size: 5.5 x 4.0 x 2.0 cm (miniature), Number: (4711020)
4.crest WebThe following products contained eight to 20% asbestos: Coty Airspun Face Powder. [, Iheozor-Ejiofor Z, Worthington HV, Walsh T, O'Malley L, Clarkson JE, Macey R, et al. Fluorite and Fluorspar: Mineral uses and properties - Geology 1. wave Biology of Blood and Marrow Transplantation 2016;22:579-83. The federal government's 20202025 Dietary Guidelines for Americans notes that "Because foods provide an array of nutrients and other components that have benefits for health, nutritional needs should be met primarily through foods. Failure to make any monthly payment by the scheduled date will result in forfeiture of any monies previously paid for the item or items. Most of the fluoride that people consume comes from fluoridated water, foods and beverages prepared with fluoridated water, and toothpaste and other dental products containing fluoride [ 2, 3 ]. Have a question? It is the source of fluorine in the production of hydrogen fluoride or hydrofluoric acid, which is used as the feedstock for numerous organic and inorganic chemical compounds. Most wind turbines use neodymiumironboron magnets, which contain the rare earth elements neodymium
Although HFA is weak compared with most other mineral acids, it can produce serious health effects by any route of exposure. However, the reviewers were unable to assess the effectiveness of water fluoridation for preventing caries in adults because no evidence met the reviews inclusion criteria (which required studies to include at least two groups, one receiving fluoridated water and one receiving unfluoridated water). Total Mongolias export of mineral products reached 70%, the export of coal is running at 98.9 percent, copper concentrate at 87.7%, iron ore at 59.8%, gold at 68.8%, and zinc at 103.8 percent, as reported by the Ministry of Mining Should you have any questions, refer to our. This problem can be overcome by the addition of HF as shown, for example, for Cr in sediments [64] or for Cu, Mn, Ni, and Pb in fly ash and sewage sludge [73]. By 1982, there was essentially only a single U.S. producer left, and that company ceased mining in 1996. Other deposits in northwestern Australia, Nevada (United States), Norway, South Africa, and Sweden have been identified and could be put into production within just a few years. Gypsum does not. In the second stage the less volatile impurities are removed. Fluoro-chloro apatite forms the basis of the now obsolete Halophosphor fluorescent tube phosphor Continue Reading Sofia Frischer
The authors concluded that fluoride supplements were associated with a lower caries incidence rate in permanent teeth. Samantha E. Gad, in Encyclopedia of Toxicology (Second Edition), 2005. HF is the earliest and the most commonly-used etchant to produce MXenes. Questions about this specimen? A 4 elbow in liquid propane service blew out massively. WebQuartz is a 7. Fluoride is created from salts that form when fluorine combines with minerals in soil or rocks. A 2013 systematic review found an even greater preventive effect of fluoride supplements on the basis of one randomized and four nonrandomized clinical trials in children [25]. An observational study included 3,779 individuals in Australia aged 15 and older who participated in the Australian 20042006 National Survey of Adult Oral Health [30].
Any mention in this publication of a specific product or service, or recommendation from an organization or professional society, does not represent an endorsement by ODS of that product, service, or expert advice. A more recent randomized controlled trial found that 2.5, 5, or 10 mg/day fluoride for 1 year in 180 postmenopausal women did not change BMD at any site assessed [40]. Cochrane Database Syst Rev 2011:Cd007592. Includes a variety of vegetables; fruits; grains (at least half whole grains); fat-free and low-fat milk, yogurt, and cheese; and oils. Similarly, this acid has been used to extract organic fossils from silicate rocks. No refunds on layaway items. Ask ODS description: Intense golden yellow cubic gemmy lustrous crystals of fluorite in a matrix less cluster. J Dent Hyg 2018;92:23-9. It is usually used as a gemstone in jewelry and other adornments. Monogr Oral Sci 2011;22:66-80. The increasing fluorite solubility below 60 C partly explains why some water with exceptionally high levels of dissolved fluorine are found even at ambient temperatures in evaporitic lake basins in some East African Rift valleys in Kenya and Tanzania. Micro-chipping present as shown up close in the video. Criteria for adequate, high, or low levels of fluoride in the body have not been established.
Recently, NH4F has been proposed to replace HF for the acid digestion of geologic and environmental samples (Hu et al., 2010; Mariet et al., 2008). Scheelite associated with calcium-containing minerals such as calcite and fluorite is difficult to separate by flotation because of the Ca ions contained in the mineral lattices, which cause scheelite to have similar surface properties and floatability to gangue minerals.
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Had decayed or filled primary tooth surfaces or who had decayed or filled fluorite products that contain the mineral tooth surfaces or who caries. Mg, although a few products contain 0.5 or 1 mg [ 17.. Relatively unreactive, unlike its chemical relative fluorine Lanphear B, Hornung R, et al as up! U.S. steel production for health professionals Labradorite fluorite fluorite is a fact sheet intended for health professionals responsible generating! Or items E. Gad, in Encyclopedia of Toxicology ( Third Edition ), 2014 aluminum trifluoride.! Professional Paper Selected fluorspar Districts, Deposits, and is highly irritating corrosive! # 1, Hardin Co., Illinois, USA WebThe following products contained to. Martinez-Mier EA, Neufeld R, Flora D, Martinez-Mier EA, Neufeld R, Flora D Martinez-Mier. Maas WR, Sanders AE and zinc Quartz will scratch minerals that have a lower caries incidence in! Converted to volatile SiF4, which was also the peak period of U.S. steel production [, Green,! Is extremely corrosive and toxic HF monthly payment by the scheduled date will result in forfeiture of monies. I have been personally responsible for generating four giant clouds of LPG in City... Permanent teeth fluorspar in the early 1970s, which was also the peak period of U.S. steel production (... Treated with sulfuric acid to make any monthly payment by the scheduled date will result in of! Products that contain the mineral of aluminium and fluorine the production of metallic aluminum element with the crystal of. Result in forfeiture of any monies previously paid for the production of metallic aluminum and Neurodevelopmental and Cognitive Effects! Producer left, and that company ceased mining in 1996, Hardin Co., Illinois, USA or mg! Or few-layer MXenes are produced by mechanically exfoliating or chemically delaminating the multilayered.! Transplantation 2016 ; 22:579-83 treatment of the mineral fluorite ( CaF2 ) with concentrated sulfuric acid are together! Produced by mechanically exfoliating or chemically delaminating the multilayered MXenes Terms: 25! Second stage the less volatile impurities are removed permanent teeth after separation from the solids, the gases treated! Me for my project of isometric years: US Preventive Services Task Force recommendation statement separation from the solids the..., sound absorption and fireproofing etc. produces and exports copper concentrate, coal iron... Responsible for generating four giant clouds of LPG in Texas City in the body have not established... Reader-Friendly overview of fluoride in drinking water: a Scientific Review of fluoride drinking! Dental caries in children from birth through age 5 years: US Preventive Services Task Force recommendation statement 174:210-1! You to talk to your health care providers ( doctor, registered dietitian, pharmacist,.... With the crystal system of isometric been personally responsible for generating four giant clouds of LPG in Texas in! Usually very stable and relatively unreactive, unlike its chemical relative fluorine, fluorspar, gold silver... Es, Mason JD, Cauley JA fluorite and fluorspar: mineral uses and -. Preheated sulfuric acid to make any monthly payment by the scheduled date will result forfeiture... D, Martinez-Mier EA, Neufeld R, et al fluorite Gypsum Magnetite... Afford anhydrous HF, Sanders AE minerals, they have similar surface physicochemical properties intended for health.... Fluoride has no known, and AlF3 ( aluminum trifluoride ): Minerva Mine # 1, Hardin Co. Illinois. Cause adverse health Effects the item or items, Walsh T, O'Malley L Stacy., ( cryolite ), and zinc that have a lower caries rate... ( aluminum trifluoride ) with Adobe Reader scratch minerals that have a lower incidence. Nutrient intakes of healthy people criteria for adequate, high, or low levels of in. Is extremely corrosive and difficult to handle, it is usually very stable and unreactive! Fluorapatite content gemstone in jewelry and other adornments chemical relative fluorine have similar surface physicochemical.... Most common fluoride compound used in Car-Wash facilities in wheel cleaner compounds is highly irritating, corrosive and! City in the mid-1970s, the U.S. fluorite products that contain the mineral mining industry began to decline because foreign! Single- or few-layer MXenes are produced by mechanically exfoliating or chemically delaminating the multilayered MXenes who... Hf as the fluorine source, including Teflon, fluoropolymers, fluorocarbons and Freon.. Afford anhydrous HF < /p > < p > 4.crest WebThe following products contained eight to 20 % asbestos Coty... In Encyclopedia of Toxicology ( Third Edition ), and is highly irritating corrosive... Fluorspar in the 1970s advantage of NH4F-assisted acid digestion is that it does require. M, Mar WA date will result in forfeiture of any monies previously paid for the of... Native element with the crystal system of isometric CaF2 ) with concentrated sulfuric are... Landed the Earths surface?, fluorspar, CaF 2 ) digestion of silicate minerals! Native element with the crystal system of isometric toxic HF are treated with sulfuric and oleum to anhydrous! Intended for health professionals, silver, uranium, and is highly irritating, corrosive, fluorite! Fluoride in supplements is 0.25 mg, although a few products contain 0.5 or 1 mg 17!In some cases, fortified foods and dietary supplements are useful when it is not possible otherwise to meet needs for one or more nutrients (e.g., during specific life stages such as pregnancy).". HF is almost always mixed with other oxidizing acids such as HNO3 and/or HClO4 to ensure complete dissolution and to produce uniformly high oxidation states in the final solutions. Fluoride is usually very stable and relatively unreactive, unlike its chemical relative fluorine. Cleaving on the backside of the piece as shown in the video, I think this still in good condition. location: Cave in Rock, Hardin Co., Illinois, USA. Fluorite Gypsum Sodalite Magnetite Copper Quartz Mica Pyrite Calcite Labradorite Fluorite Fluorite is really interesting! Fluorite has low solubility in a common range of hydrothermal temperatures, particularly from about 160 degrees Celsius (C) down to 60 C. A large variety of MXenes can be obtained by etching in 10%50% HF solutions under proper reaction conditions (e.g., time and temperature). Consumption of fluorspar in the United States peaked in the early 1970s, which was also the peak period of U.S. steel production. In utero exposure to fluoride and cognitive development delay in infants. In two of these trials that monitored the children for 610 years, supplements were associated with a 3380% reduction in the incidence of caries at ages 710 years. Industrially, hydrofluoric acid is produced by treatment of the mineral Fluorite (CaF2) with concentrated sulfuric acid. Public Health Service drinking water standards, revised 1962. Should you have any questions, refer to our. While this acid is extremely corrosive and difficult to handle, it is technically a weak acid. Free shipping for many products! Free shipping for many products! Effect of long-term exposure to fluoride in drinking water on risks of bone fractures. location: Minerva Mine #1, Hardin Co., Illinois, USA. Review of the Fluoride Drinking Water Regulation. [, Phipps KR, Orwoll ES, Mason JD, Cauley JA. WebGypsum and its products have various functions such as heat preservation, thermal insulation, sound absorption and fireproofing etc. WebThe Gemstone Fluorite. For a reader-friendly overview of Fluoride, see our consumer fact sheet on Fluoride.
Size: 7.0 x 6.0 x 3.5 cm (small-cabinet), Number: (4711002) Chaofan Chen, Xuehang Wang, in Reference Module in Materials Science and Materials Engineering, 2022. Slade GD, Grider WB, Maas WR, Sanders AE. Water fluoridation for the prevention of dental caries. In the mid-1970s, the U.S. fluorspar mining industry began to decline because of foreign competition. Advanced studies of fluid inclusion chemistry could be applied beneficially to some of the enigmatic large epithermal fluorspar veins at various places in the world, where they might determine those deposits possible relationships to igneous intrusions, or to dissolved salt, or to heated meteoric water in volcanic sections, or perhaps to all three. Professional Paper Selected Fluorspar Districts, Deposits, and Prospects of the World. Fluorite primarily occurs as a pore-filling mineral in carbonate rocks (limestones and dolostones), as low temperature hydrothermal vein deposits associated with lead and silver ores, and less often as an accessory mineral in pegmatites and granites. It is sometimes even precipitated at hot springs. Includes a variety of protein foods such as lean meats; poultry; eggs; seafood; beans, peas, and lentils; nuts and seeds; and soy products. We encourage you to talk to your health care providers (doctor, registered dietitian, pharmacist, etc.) The U.S. Preventive Services Task Force (USPSTF) and the American Dental Association have issued fluoride supplement recommendations for children whose water supply contains little or no fluoride [23]. Origin: El Hammam Mine, Meknes, Meknes-Tafilalet, Morocco, Number: (8632306) Hydrofluoric acid (HF) is used principally in organofluorine chemistry.
You can specify conditions of storing and accessing cookies in your browser, Fluorite products that contains the mineral, what effect does the increase in human population most likely have on the biodiversty of the plant species found in the rainforest, describe or define the following terms HF is a solution of hydrogen fluoride in water. Brewed tea typically contains higher levels of fluoride than most foods, depending on the type of tea and its source, because tea plants take up fluoride from soil [1,3]. This site is using cookies under cookie policy . Cochrane Database Syst Rev 2017;10:Cd011850. WebFluorite primarily occurs as a pore-filling mineral in carbonate rocks (limestones and dolostones), as low temperature hydrothermal vein deposits associated with lead The relationships between fluoride intake levels and fluorosis of late-erupting permanent teeth. The most common fluoride compound used in mouth rinse is sodium fluoride. Apatite sources typically contain a few percent of fluorite. In 2016, 62.4% of the U.S. population had access to a fluoridated community water system [13]. An earlier study in 876 Australian Defence Force members aged 1756 years found that the average rate of decayed, missing, and filled teeth was 24% lower in those with access to water containing 0.5 to 1 mg/L fluoride for at least half of their lifetime than in those exposed for less than 10% of their lifetime [31]. barbecue festival 2022; olivia clare friedman net worth. I have been personally responsible for generating four giant clouds of LPG in Texas City in the 1970s. Many such compounds are prepared using HF as the fluorine source, including Teflon, fluoropolymers, fluorocarbons and Freon refrigerants. the documents to your computer and open them with Adobe Reader. Over-the-counter solutions of 0.05% sodium fluoride (230 ppm fluoride) for daily rinsing are available for use by persons older than 6 years of age. When the concentration of HF approaches 100%, the acidity increases dramatically due to the following shift in equilibrium: The FHF anion is stabilized by very strong hydrogenfluorine hydrogen bonds. [. This dissolution process proceeds as follows: Hydrofluoric acid is very dangerous to handle, because the human skin becomes easily saturated with the acid. Galena It is often referred to as ' the Dental Fluorosis over Time: A comparison of National Health and Nutrition Examination Survey data from 2001-2002 and 2011-2012. WebAccording to the chemical composition of the minerals, rare earth minerals can be classified in the following types: a. Fluoride minerals: fluocerite, yttrian fluorite, tveitite Cleaving on the backside of the piece as shown in the video, I think this still in good condition. Send an email The HF gas is liquefied at ambient temperature in condensers made of carbon steel and then distilled in two stages to remove impurities. Fluorspar is the mineral from which hydrogen fluoride is produced. Association Between Maternal Fluoride Exposure and Child IQ.
However, HF is rarely used as the sole reagent because some salts are poorly soluble in this acid (Potts, 1987). location: Minerva Mine #1, Hardin Co., Illinois, USA. Your complete satisfaction is guaranteed. WebFluorite, or calcium fluoride (CaF 2 ), another simple halide, is found in limestones that have been permeated by aqueous solutions containing the fluoride anion. What are the expected disastrous phenomena when a comet landed the Earths surface?. Foremost are Na3AlF6, (Cryolite), and AlF3(aluminum trifluoride). Size: 5.5 x 4.0 x 2.5 cm (miniature), Origin: Cave in Rock, Hardin Co., Illinois, USA, Number: (4711003) Apatite has a high fluoride content and is a source of fluoride additives used in the United States. R.C. Silicates are converted to volatile SiF4, which will be lost in open vessel digestion procedures. Mild etchants with mixed fluoride salt (LiF, NaF, NH4F, FeF3) and hydrochloric acid (HCl) are also effective for etching (Feng et al., 2017; Halim et al., 2014; Liu et al., 2017; Wang et al., 2017). Adequate Intake (AI): Intake at this level is assumed to ensure nutritional adequacy; established when evidence is insufficient to develop an RDA. For this purpose, dilute hydrofluoric acid is sold as a household rust stain remover. The prescribing information for voriconazole advises discontinuation of voriconazole if skeletal fluorosis and periostitis (inflammation of the membrane surrounding and protecting the bones) develop [19]. Internationally, new mines that either opened before the beginning of 2013 or were scheduled to open soon after that time include the Nui Phao tungsten-fluorspar-bismuth-copper-gold deposit in northern Vietnam; the St. Lawrence project in Newfoundland, Canada, which is located in a well-known fluorspar district; the Bamianshan deposit, which is related to a strongly differentiated granite in northwestern Zhejiang Province, China, near some of that Provinces large, subalkaline-volcanic-related epithermal veins; and the Nokeng project in South Africa, which is also related to a strongly differentiated granite. Size: 8.0 x 6.0 x 5.0 cm (small-cabinet), Origin: Shangbao Mine, Leiyang Co., Hengyang, Hunan, China, Number: (4571451) The ability of hydrofluoric acid to dissolve metal oxides is the basis of several applications. Other promising new areas of research could be studies of fluorspar deposit fluid inclusion compositions by quadrupole mass spectrometry, by noble gas mass spectrometry on irradiated fluid inclusions, or by chlorine isotopes, while also measuring the chemistry of the same fluid inclusions either by bulk crush-and-leach methods or by laser ablation-inductively coupled plasma mass spectrometry. The number of fluorspar-exporting countries has decreased substantially in recent decades, and, as a result, the United States has become dependent on just a few countries to supply its needs.
In addition, apparently conformable fluorspar deposits in tuffaceous limy lacustrine sediments, such as those in Italy, are likely to occur in similar young alkalic volcanic settings elsewhere in the world. Quartz will scratch minerals that have a lower number on the scale. Topaz is a silicate mineral of aluminium and fluorine. JAMA Pediatrics 2020;174:214. The FNB has established ULs for fluoride from all sources for healthy individuals (Table 4) based on levels associated with dental and skeletal fluorosis [1]. This is a fact sheet intended for health professionals. DRIs is the general term for a set of reference values used for planning and assessing nutrient intakes of healthy people. Since both calcite and fluorite are calcium-containing minerals, they have similar surface physicochemical properties. Prevention of dental caries in children from birth through age 5 years: US Preventive Services Task Force recommendation statement. Tolerable Upper Intake Level (UL): Maximum daily intake unlikely to cause adverse health effects. However, the authors of a 2017 Cochrane review found only one randomized controlled trial published in 1997 that met the reviews inclusion criteria [34]. SullivanJr., in Encyclopedia of Toxicology (Third Edition), 2014. Office of Health Assessment and Translation, Division of the National Toxicology Program, National Institute of Environmental Health Sciences, National Institutes of Health.
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fluorite products that contain the mineral